Evaluation of water-salt regime parameters for the Inhulets river in the technogenic affected zone based on hydrochemical monitoring data

Dmytro Rudakov
Dnipro University of Technology, Dnipro
https://orcid.org/0000-0001-7878-8692

Olha Chehun
Regional Office of Water Resources in Dnipropetrovsk Region, Dnipro
https://orcid.org/

Yurii Bytko
Dnipro University of Technology, Dnipro
https://orcid.org/0009-0006-1877-9587

DOI:

Keywords: water-salt regime, technogenic impact, river flow rate, underground runoff, anion content

Abstract

The need to supply consumers with adequate quality water in the south of the Dnipropetrovsk region and water for irrigation in the Kherson and Mykolaiv regions requires thorough studying the features of the water-salt regime of the technogenically mostly loaded section of the Inhulets River, which is the purpose of this paper. Unlike previous studies of this section of the Inhulets River, which dealt primarily with average concentrations in river water and long-term trends, an analysis of state water monitoring data was conducted with a frequency of once every 1–3 months, involving data on daily water flows in two sections for 6 years along with results from satellite surveying, the state hydrochemical monitoring data were analyzed to study the water-salt regime of the Inhulets River within the section of approximately 70 km length, situated between the Karachunivske dam reservoir and the village of Andriyivka. 22 short periods in 2014–2019 were examined in detail, during which the flow rate of the Inhulets River, discharges from the Saksahanske reservoir, and the anion contents in water in the upper and lower reaches of the river section were measured. Statistical analysis with water-salt balance equations assessed the technogenic and natural factors influencing the discharge of the Inhulets River and the increase in its water salinity. It was found that the anion content in river water after passing through the studied section during periods without extensive mine-water discharges increases by almost 1.5 times. This gives a quantitative assessment of the technogenic impact on the hydrogeochemical regime in the considered part of the Inhulets River valley. The share of chlorides in river water increases after passing through this area, on average, from 20–22% to 38% during periods without mine water discharges and 68% during periods with discharges from the mine water storage pond. The practical significance of the results is determined by the quantitative assessment of water losses and changes in water quality when using this section of the Inhulets Riverbed to transport fresh water to the southern areas of the Dnipropetrovsk region, where water supplies were disrupted following the destruction of the Kakhovka HPP dam.

References

1. Bahrii, I. D., Hozhyk, P. F., & Samotkal, Ye. V. (2005). Hidrosystema Kryvorizkoho baseinu: stan i napriamky polipshennia. Feniks. [in Ukrainian]

2. Bolotin, L. A., Summers, B. M., Savoy, Ph. & Blaszczak J. R. (2023). Classifying freshwater salinity regimes in central and western U.S. streams and rivers. Limnology and Oceanography Letters. 8, 103–111. https://doi.org/10.1002/lol2.10251

3. Cañedo-Argüelles, M., Kefford, B. & Schäfer, R. (2019). Salt in freshwaters: causes, effects and prospects - introduction to the theme issue. Philos Trans R Soc Lond B Biol Sci. 374(1764): 20180002. https://doi.org/10.1098/rstb.2018.0002

4. Derzhavne ahentstvo vodnykh resursiv Ukrainy. (2026). Monitorynh ta ekolohichna otsinka vodnykh resursiv Ukrainy. http://monitoring.davr.gov.ua/EcoWaterMon/GDKMap/Index [in Ukrainian]

5. GIZ Ukraina. (2017). Optymizatsiia skydannia ta utylizatsiia nadlyshku shakhtnykh vod (Report No. 20669066/1). [in Ukrainian]

6. Hocking, C. & Bailey, R.T. (2022). Salt transport in a large agro-urban river basin: Modeling, controlling factors, and management strategies. Front. Water 4:945682. https://doi.org/10.3389/frwa.2022.945682

7. Khilchevskyi, V. K., Romas, I. M., Romas, M. I., Hrebin, V. V., & Shevchuk, I. O. (2007). Hidroloho-hidrokhimichna kharakterystyka minimalnoho stoku richok baseinu Dnipra. Nika-Tsentr. [in Ukrainian]

8. Khilʹchevsʹkyy, V. K., Kravchynsʹkyy, R. L. & Chunarʹov, O. V. Hidrokhimichnyy rezhym ta yakistʹ vody Inhulʹtsya v umovakh tekhnohenezu (2012). Nika-Tsentr. [in Ukrainian]

9. Linacre, E. T. (1977). A simple formula for estimating evaporation rates in various climates, using temperature data alone. Agricultural Meteorology, 18(6), 409–424. https://doi.org/10.1016/0002-1571(77)90007-3

10. Mitko, K., Dydo, P., Milewski, A. K., Bok-Badura, J., Jakóbik-Kolon, A., Krawczyk, T., Cieplok, A., Krodkiewska, M., Spyra, A., Gzyl, G., et al. (2024). Mine Wastewater Effect on the Aquatic Diversity and the Ecological Status of the Watercourses in Southern Poland. Water, 16(9):1292. https://doi.org/10.3390/w16091292

11. NASA. (2025). Prediction of worldwide energy resources. https://power.larc.nasa.gov/data-access-viewer/

12. Perri, S., Suweis, S., Holmes, A., Marpu, P. R., Entekhabi, D. & Molini A. (2020). River basin salinization as a form of aridity, Proc. Natl. Acad. Sci. U.S.A. 117(30), 17635-17642, https://doi.org/10.1073/pnas.2005925117

13. Raion Kakhovka. (2024, 25th August). Pidriv Kakhovskoi HES: Yak menshe, nizh za rik, vdalosia pobuduvaty mahistralnyi vodohin na Kryvyi Rih. https://kakhovka.rayon.in.ua/news/735380-pidriv-kakhovskoi-ges-yak-menshe-nizh-za-rik-vdalosya-pobuduvati-magistralniy-vodogin-na-kriviy-rig [in Ukrainian]

14. Rudakov, D.V. & Bytʹko Yu. M. (2025). Statystychnyy analiz hidrolohichnykh protsesiv v baseyni r. Samara v umovakh klimatychnykh zmin. Zbirnyk naukovykh pratsʹ NHU, 82, 55-64. https://doi.org/10.33271/crpnmu/82.139

15. Rudakov, D., Sun, Y. & Inkin, O. (2024). Optimization of mine water discharge with the river hydrograph. Case study Samara River in Western Donbas. IOP Conf. Series: Earth and Environmental Science. 2024. 1348. 012041. https://doi.org/10.1088/1755-1315/1348/1/012041

16. Sherstiuk N. P., Khilchevskyi V. K. & Zabokrytska, M. R. (2023). Environmental risk assessment of Kryvbas mine water discharges into the Inhulets River. EAGE Conf. Proc., 17th International Conference Monitoring of Geological Processes and Ecological Condition of the Environment, Vol. 2023, 1–5 https://doi.org/10.3997/2214-4609.2023520002

17. Sherstiuk, N. P., & Khilchevskyi, V. K. (2012). Osoblyvosti hidrokhimichnykh protsesiv u tekhnohennykh ta pryrodnykh vodnykh obiektakh Kryvbasu. Aktsent PP. [in Ukrainian]

18. Sherstiuk, Ye. A. (2021). Heotekhnichna stiikist porodnykh masyviv v zoni vplyvu tekhnohennoho vodoobminu hirnychorudnoho kompleksu (PhD thesis, NTU “Dniprovska politekhnika”). [in Ukrainian]

19. Snizhko, S., Shevchenko, O., & Didovets, Yu. (2021). Analiz vplyvu klimatychnykh zmin na vodni resursy Ukrainy. Ekodiia. [in Ukrainian]

20. Stepanenko, S. M., Polovyi, A. M., Loboda, N. S., et al. (2015). Klimatychni zminy ta yikh vplyv na sfery ekonomiky Ukrainy. TES. [in Ukrainian]

21. Suspilne Dnipro. (2024, 6th June). Bez “moria” ta vody: Yak zhyteli Dnipropetrovshchyny cherez pidryv Kakhovskoi HES zalyshylysia bez vodopostachannia. https://suspilne.media/dnipro/762103-bez-mora-ta-vodi-ak-ziteli-dnipropetrovsini-cerez-pidriv-kahovskoi-ges-zalisilisa-bez-vodopostacanna/ [in Ukrainian]

22. Wang, G., Xu, B., Tang, P., Shi, H., Tian, D., Zhang, C., Ren, J. & Li, Z. (2022). Modeling and Evaluating Soil Salt and Water Transport in a Cultivated Land–Wasteland–Lake System of Hetao, Yellow River Basin’s Upper Reaches. Sustainability. 14(21):14410. https://doi.org/10.3390/su142114410

23. Winde, F., Newman-Portela, A. M. (2026). Assessing Mining-Related Water Impacts: A Case Study-Based Systematic Review Supporting a More Comprehensive Approach. Sustainability. 18(4):1774. https://doi.org/10.3390/su18041774

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